Collection Occupational hygiene, Issue 21, 1985 year
Gas chromatographic determination of trace amounts of pesticides - derivatives of thiocarbamic acid in the air
L. G. Alexandrova
doi
Kiev Research Institute of Occupational Hygiene and Occupational Diseases
Full article (PDF)
In agriculture, thiocarbamic acid derivatives vernam (N, N. S-tripropylthiocarbamate), ronite (SN-diethyl-N-cyclohexylthiocarbamate), sutan (S-ethyl-N, N- (diisobutyl) thiocarbamate), tillam (N- butyl-S-propyl-N-ethylthiocarbamate), eptam (N, N-dipropyl-S-ethylthiocarbamate), yalan (N-hexamethylene-S-ethylthiocarbamate) as herbicides against annual weeds in crops of corn, beets (sugar, fodder and canteen), rice (yalan) and other crops. These herbicides belong to medium- and low-toxic compounds, their MPC in the air of the working area ranges from 0.5 (yalan) to 5 (vernam) mg / m3.
The gas chromatographic method for determining microamounts of thiocarbamates is suitable for sanitary and hygienic control over the content of these pesticides in the air of the working area. Methodological guidelines for the determination of residual amounts of thyocarbamates in the air were approved by the Deputy Chief State Sanitary Doctor of the USSR on 06/05/1978, No. 1877 [2].
References
- Aleksandrova L. G. Opredeleniye ronita v vozdukhe rabochey zony, rastitel'nom materiale i biologicheskikh sredakh. — Occupational hygiene, 1975, vyn. 11, s. 135—139.
- Klisenko M. A., Kofman I. SH., Kofanov V. I., Aleksandrova L. G. Metodicheskiye ukazaniya po opredeleniyu gerbitsidov — proizvodnykh tiokarbami- novoy kisloty (vernam, ronit, sutan, tillam, eptam, yalan) v vode, pochve, rastitel'nom materiale, biosubstratakh i vozdukhe gazokhromatograficheskim metodom. — V kn.: Metod, ukazaniya po opredeleniyu mikrokolichestv pestitsidov v produktakh pitaniya, kormakh i vneshney srede. M.: B. i., 1980, ch. 10, s. 117—127.
- Khokhol'kova G. A., Voloshina E. I. Obnaruzheniye tillama i eptama v vozdukhe i krovi metodom khromatografii v tonkom sloye. — V kn.: Metody analiza.: Tr. II Vsesoyuz. soveshchaniya po issledovaniyu ostatkov pestitsidov i profilaktike zagryazneniya imi produktov pitaniya, kormov i vneshney sredy. Tallin: B. i., 1971, s. 210—212.